Search results for "schiff-base ligands"

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From magnetic to nonlinear optical switches in spin-crossover complexes

2013

ISI Document Delivery No.: 109TF Times Cited: 0 Cited Reference Count: 173 Lacroix, Pascal G. Malfant, Isabelle Real, Jose-Antonio Rodriguez, Vincent Wiley-v c h verlag gmbh Weinheim Si; Various attempts to combine magnetic and nonlinear optical (NLO) properties in a molecule are reviewed, with a special focus on the possibility of interplay between the magnetic component and the quadratic (proportional to E-2) NLO response. This multidisciplinary research leads to the idea of spin-crossover-induced (SCO-induced) NLO switching and is evaluated at the synthetic level, with insights provided by computational chemistry. The need for nontraditional experimental setups to record NLO properties i…

Computational chemistryNonlinear opticsroom-temperaturetransition-metal-complexesSolid-stateNanotechnology02 engineering and technology010402 general chemistry01 natural scienceselectrical-conductivityInorganic ChemistryNonlinear opticalQuadratic equationSpin crossoverbinuclear iron(iii) complexesMagnetic componentsMoleculenlo propertiesNuclear Experimentliquid-crystalCondensed matter physicsChemistryNonlinear optics021001 nanoscience & nanotechnologySpin crossoverMaterials science0104 chemical sciences2nd-harmonic generationHigh Energy Physics::Experimentschiff-base ligandsray crystal-structure0210 nano-technologyFocus (optics)hyper-rayleigh scatteringMolecular devices
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